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Environmentally friendly adhesive raw materials for a long shoe life


Bayer Material Science offers a large portfolio of polyurethane and polychloroprene raw materials for adhesives, that offer excellent solutions for high quality athletic and street shoes. Polyurethane- and polychloroprene based adhesives show good adhesion on a multitude of substrates and satisfy the most demanding quality requirements. They can be formulated as one- or two-component systems and these raw materials are available for use in solvent- or waterbased adhesives.










Waterborne adhesive raw materials: polyurethane dispersions, polychloroprene dispersions

A growing sensibility towards the environment and more stringent regulations in many countries have resulted in a strongly growing demand for environmentally friendly adhesive systems. Bayer MaterialScience provides a multitude of raw materials to satisfy this demand. There are waterbased polyurethane dispersions (Dispercoll® U -range) as well as polychloroprene dispersions (Dispercoll® C-range), that are offering a property profile that matches the ones of traditional, solvent-based systems. In some properties they even offer significant advantages.

Dispercoll® U - Polyurethane dispersions for thermo-activatable shoe adhesives
    Polyurethane dispersions of the Dispercoll® U-range contain a high-molecular weight polyurethane dispersed in water. It de-crystallizes at temperatures of more than 50°C and becomes tacky. These dispersions can be formulated as one- or two-component systems. A two-component system formulated by adding a polyisocyanate like one of the Desmodur® D-range results in a crosslinking and ultimately offers an increased durability, so adhesives last longer and offer a better mechanical resistance. This makes them particularly suitable for shoe sole applications.

    The major properties and advantages of Dispercoll® U are:


      • Excellent initial strength even if applied wet in wet
      • Fast increase of strength
      • Highly fillable
      • Can be formulated to high softening points without use of Isocyanates
      • Very good resistance against humidity, oil and chemicals

    The properties of the final adhesive can be further enhanced by the addition of polyisocyanates like the ones of the Desmodur® D-range in a two-component system.

    More detail information on Dispercoll® U
    More on the thermo-activation process here
    Fore an overview on our Dispercoll® U waterbased dispersions, have a look at this two-page summary: Dispercoll® C - Polychloroprene dispersions for contact adhesives in shoe applications
      Polychloroprene dispersions of the Dispercoll® C-range are used as contact adhesives and can be formulated as one- or two-component systems. They can be formulated as contact adhesives which are particularly suitable for the bonding of the upper shoe and the inner sole. Dispercoll® C has a low monomer content and provides the following properties to the shoe adhesive system:
        • Long open times
        • Immediate good adhesion
        • Rapid build-up of bond strength
        • Solvent-free
        • Very good resistance against humidity, oils and chemicals
      Some product examples for this application:

      Type
      Solids in %
      pH
      Viscosity mPas at 23°C
      Characteristics
      Polyurethane dispersions
      Dispercoll® U 54
      Polyurethane dispersion
      50
      7,5
      300
      Waterbased polyurethane dispersion for thermo-activatable adhesives, particularly for shoe sole applications
      Polyisocyanate crosslinker for polyurethane dispersions
      Desmodur® DN
      Polyisocyanate
      100
      -
      1250
      Isocyanate crosslinker for
      Dispercoll® U

      TypeSolids in %pHViscosity mPas at 23°CCharacteristics
      Polychloroprene dispersions
      Dispercoll® C 74
      Polychloroprene
      dispersion
      58
      13.0
      100
      Waterbased polychloroprene dispersion for upper shoe and inner sole applications
      Dispercoll® C 84
      Polychloroprene
      dispersion
      55
      13.0
      100
      Waterbased polychloroprene dispersion for upper shoe and inner sole applications
      Polyisocyanate crosslinker for polychloroprene dispersions
      Bayhydur®
      401-70
      Polyisocyanate
      crosslinker
      70
      13.4
      600
      Waterbased Isocyanate crosslinker for
      Dispercoll® C


      Solvent-based adhesive grades: Baypren®, Desmocoll®, Desmodur® R

      Solvent-based polyurethane adhesive raw materials of the Desmocoll® -range are used to formulate thermo-activatable adhesives that can be applied as a one- or two component system. Another group of raw materials in this category are the polychloroprene adhesive grades of the Baypren®-range which can be formulated into contact adhesives. As with the above described raw materials, these grades can be modified as well to obtain specific properties like a higher durability or an enhanced resistance by a post-reaction with Desmodur® R-grades.

      Some product examples:

      Type
      Characteristics
      Baypren® 320/1
      Polychloroprene rubber
      Typical raw material for formulation of contact adhesives
      Desmodur® R
      Polyisocyanates
      Desmocoll® range
      Linear hydroxy-
      Polyurethanes
      These products represent just a fraction of our entire product line. To find all products of a particular product range, please use the "Products by Trade Name" function.

      Press Release: Bayer MaterialScience develops “green shoe” concept

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