Nomenclature Bayhydrol®

K 2010
Technologien

Very high solid systems with polyaspartics (polyaspartic acids)


Polyaspartics (polyaspartic acids) represent a class of binders that combine low VOC properties with high productivity, while at the same time maintaining the quality requirements users expect from polyurethane coatings.



For more details about the performance triangle and the chemistry of polyaspartics please read the article "Polyaspartics - innovative binders for cost-effective coating design" by SCI Magazine, Issue 2009/3.
      Abstract:

      Low VOC content - Environmental friendlyness
      Reducing solvent emissions to a minimum has been an ongoing objective to develop environmentally friendly coatings systems and to comply with current VOC regulations. The low viscosity properties of polyaspartic binders - some down to below 100 mPas - make it possible to formulate "ultra high solid" coatings that can still be applied easily with the equipment regularly used in corrosion protection and industrial coating areas.

      Meeting increased cost pressure
      There is a growing tendency to reduce cost to the endusers of corrosion protection and other industrial coating applications. This can be met by increasing the productivity of the entire coating process. Polyaspartics make it possible to contribute to cost efficiency in two ways:

        • Reduced drying times

          Coating systems based on polyaspartic acids are dry in 1 1/2 to 4 hours at room temperature, depending on the environmental conditions. So the application of the layers is accelerated significantly.

        • Greater film thickness

          A dry film of up to 400 µm thick can be obtained in a single coating operation, so the number of coating layers can be reduced, in many cases by one layer in the entire coating built-up.

      Maintaining high quality
      On top of the environmental requirements and the need to reduce cost the property profile of the coatings still needs to be at the same high level people expect from polyurethane systems. The protective properties are critical for the longevity of steel structures and a good gloss retention is desirable even in severe weather exposure. In general, the typical high quality performance of polyurethane coatings are easily met (i.e. durability, flexibility, ect.) with polyaspartics on a variety of different substrates.
Product examples of Polyaspartics:

Solids
in %
Equivalent weight
Viscosity
mPas at 25°C
Reactivity
Desmophen® NH 1520
100
290
~ 1500
+
Desmophen® NH 1420
100
279
~ 1500
++
Desmophen® NH 1220
100
230
< 100
++++
Desmophen® NH 1521
90 % in BA
326
~ 150
+

Polyaspartic acids are cured with aliphatic polyisocyanates. The potlife and reactivity of the formulation can be finetuned exactly by selecting the appropriate Desmophen® NH component.

Some suitable polyisocyanate crosslinkers (Examples)

Solids in %
Viscosity mPas
at 23°C
NCO-Content [%]
Functionality
Desmodur® N 3900
100
700
23,7
> 3
Desmodur® N 3600
100
1200
23
> 3
Desmodur® N 3390 BA
90 in Butylacetate
500
19,6
> 3
Desmodur® N 75 BA
75 in Butylacetate
170
16,5
> 3


Get more information on polyaspartics in this presentation:
"Polyaspartics - Modern Binders for highly efficient 2K PUR Systems"

About the chemistry of polyaspartics (polyaspartic acids)
A polyaspartic is an aliphatic polyurea (reaction product of an aliphatic polyisocyanate with an aspartic ester). Aspartic esters are sterically hindered, secondary aliphatic amine. However, coatings based on polyaspartics are very different in both application and coating performance properties from conventional polyureas.

Polyaspartics are not blocked, they are odorless and compatible with most other resins. Due to their aliphatic character the coatings exhibit a good weatherability.


This technology is primarily used in coatings for corrosion protection, for commercial vehicles, ACE (Agricultural, Construction, Earth Moving Equipment), in windmill power plants and in the construction industry, to just name a few examples.


More information on polyaspartics is available in these articles:

Polyaspartics for Corrosion Protection Applications

Chemical Resistance of Polyaspartic Ester-based Coatings


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